Chap. 15 - BaTiO3 films for multilayer devices by tape casting
Keywords:
BaTiO3, Tape Casting, Nanoparticles, Rheology, Temperature, RoughnessAbstract
The diversity of the applicational scope of modern printed electronics relentlessly requires the improvement of operational properties simultaneously with reducing the overall dimensions of devices. One of the most effective ways to overcome this major obstacle is the reduction of functional layers thickness in respect to the size of the device. In the present article, we are discussing a simple way of practical implementation of miniaturization concept through the application of a well-known high-productive industrial method of tape casting for obtaining thin nanostructured ceramic layers based on BaTiO3 nanopowders for MLCC. Using of nanosized powders per se imply a new approach of developing suspensions with suitable rheology for tape casting. We demonstrate, that a length of polymer molecule defines the size of floccules and therefore influences the thickness and surface quality of tape casted films. A certain nanopowder/polymer ratio contributes to the formation of the tapes with the surface roughness comparable with the size of one nanoparticle (20-25 nm). Moreover, it was established that developed suspensions are extremely sensitive to temperature changes. Lowering the temperature significantly affects the flow character of suspension and thus the thickness of casted tapes. Considering this fact, we propose an effective self-developed pre-cooling method of nanopowder suspension casting, which allows obtaining extremely thin and smooth tapes with a thickness of less than 1 µm and surface roughness of 20–25 nm by tape casting method.
References
????????? ??, ??????? ??, ???????????? ??, ?????? ??. ????????? ??????
????????? ?????????? ?????? ?? ?????? ??????????? BaTiO3 ???????
?????????? ?????. ???????? ????? ? ?????. 2016;4:55–66.
Mistler RE, Twiname ER. Tape casting?: theory and practice. American Ceramic Society; 2000. 298 p.
Chu LW, Prakash KN, Tsai MT, Lin IN. Dispersion of nano-sized BaTiO3 powders in nonaqueous suspension with phosphate ester and their applications for MLCC. J Eur Ceram Soc. 2008;28(6):1205–12.
Sakabe Y, Wada N, Ikeda J, Hamaji Y. Ceramics for ultra-thin dielectric layer of multilayer ceramic capacitors. IEEE Int Symp Appl Ferroelectr. 1998;565–9.
Randall M, Skamser D, Kinard T, Qazi J, Tajuddin A, Trolier-McKinstry S, et al. Thin film MLCC. In: CARTS-CONFERENCE-. 2007. p. 403.
Umerova S, Ragulya A. Shear Thickening of BaTiO3 Nanoparticles-Filled Non-Newtonian Polymer Suspensions. Rheol open access. 2017;1(1):6.
Umerova SO, Ragulya A V. Temperature dependent rheology of plasticized polymer suspensions filled with ceramic nanoparticles. Appl Rheol. 2018;28(4).
Seal A, Chattopadhyay D, Das Sharma A, Sen A, Maiti HS. Influence of ambient temperature on the rheological properties of alumina tape casting slurry. J Eur Ceram Soc. 2004;24(8):2275–83.
Sofie SW. Fabrication of Functionally Graded and Aligned Porosity in Thin Ceramic Substrates With the Novel Freeze Tape-Casting Process. J Am Ceram Soc [Internet]. 2007 Jul 1 [cited 2020 Apr 22];90(7):2024–31. Available from: http://doi.wiley.com/10.1111/j.1551-2916.2007.01720.x
Cahn RW, Haasen P, Kramer EJ, Brook RJ. Materials science and technology?: a comprehensive treatment.Vol. 17A, Processing of ceramics, Part 1. VCH; 1996.
Rahaman MN. Ceramic processing and sintering. 2nd ed. CRC Press; 2017. 875 p.
Ivanchenko SE, Dulina IO, Umerova SO, Nikulin AG, Ragulya A V. Formulation and rheology of tape casting suspensions based on BaTiO3 nanopowders. In: Springer Proceedings in Physics. Springer Science and Business Media, LLC; 2015. p. 193–202.
Tsurumi T, Hoshina T, Takeda H, Mizuno Y, Chazono H. Size effect of barium titanate and computer-aided design of multilayered ceramic capacitors. In: IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control. 2009. p. 1513–22.
Choi SH, Kim ID, Hong JM, Park KH, Oh SG. Effect of the dispersibility of BaTiO3 nanoparticles in BaTiO3/polyimide composites on the dielectric properties. Mater Lett. 2007 May;61(11–12):2478–81.
Polishko I, Ivanchenko S, Horda R, Brodnikovskyi Y, Lysunenko N, Kovalenko L. Tape casted SOFC based on Ukrainian 8YSZ powder. In: Materials Today: Proceedings. Elsevier Ltd; 2019. p. 237–41.
Kolesnichenko VG, Zamula M V., Yurchenko Y V., Chudinovych O V., Makogon VA, Tyschenko NI, et al. Spark Plasma Sintering of Magnesium Fluoride Nanopowders. Powder Metall Met Ceram. 2019 Nov 1;58(7–8):406–15.
Ragulya A V., Polotay A V. Non-isothermal sintering of barium titanate nano-powders of different origination. In: Ferroelectrics. Gordon and Breach Science Publishers Inc.; 2001. p. 41–51.
Liang Y, Ozawa M, Krueger A. A general procedure to functionalize agglomerating nanoparticles demonstrated on nanodiamond. ACS Nano. 2009 Aug 25;3(8):2288–96.
Robertson CG, Lin CJ, Rackaitis M, Roland CM. Influence of Particle Size and Polymer?Filler Coupling on Viscoelastic Glass Transition of Particle-Reinforced Polymers. Macromolecules [Internet]. 2008 Apr [cited 2020 Feb 3];41(7):2727–31. Available from: https://pubs.acs.org/doi/10.1021/ma7022364
Cho CW, Cho YS, Yeo JG, Kim J, Paik U. Effects of PVB on the gelation behavior of BaTiO3-based dielectric particles and glass suspension. J Eur Ceram Soc. 2003;23(13):2315–22.
Cho YS, Yeo JG, Jung YG, Choi SC, Kim J, Paik U. Effect of molecular mass of poly(vinyl butyral) and lamination pressure on the pore evolution and microstructure of BaTiO3 laminates. Mater Sci Eng A. 2003 Dec 5;362(1–2):174–80.
Otsubo Y. Effect of polymer adsorption on the rheological behavior of silica suspensions. J Colloid Interface Sci. 1986;112(2):380–6.
Hellebrand H. Tape Casting. In: Materials Science and Technology [Internet]. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA; 2006 [cited 2020 Feb 3]. Available from: http://doi.wiley.com/10.1002/9783527603978.mst0192
Ivanchenko SE, Polishko ?O, Baranovskyi DI, Brodnikovskyi YM, Vasylyev OD,
Ragulya A V. Tape Casting of anode and electrolyte layers for solid oxide fuel cells.
?????????? ???????? ?? ????????? (??????? ????????? ??????? ????????????????? ?? ?? ??????????). 2018;1(1):65–72.
Bulatova R, Jabbari M, Kaiser A, Della Negra M, Andersen KB, Gurauskis J, et al. Thickness control and interface quality as functions of slurry formulation and casting speed in side-by-side tape casting. J Eur Ceram Soc. 2014;34(16):4285–95.
Liu S, Shen Q, Luo G, Li M, Zhang L. Calculation of tape thickness for ceramic tape casting. Key Eng Mater. 2012;512(515):328–33.
Jabbari M, Bulatova R, Tok AIY, Bahl CRH, Mitsoulis E, Hattel JH. Ceramic tape casting: A review of current methods and trends with emphasis on rheological behaviour and flow analysis. Vol. 212, Materials Science and Engineering B: Solid-State Materials for Advanced Technology. Elsevier Ltd; 2016. p. 39–61.
Umerova SO, Dulina IO, Ragulya A V. Formation Features of Thin Bilayer Objects «Conductor-dielectric» Obtained by Screen Printing Method. Nanomater Appl Prop. 2014;3(1):1–04.
Heller JP. An Unmixing Demonstration. Am J Phys [Internet]. 1960 Apr 20 [cited 2020 Apr 20];28(4):348–53. Available from: http://aapt.scitation.org/doi/10.1119/1.1935802
Matveenko VN, Kirsanov EA. The viscosity and structure of dispersed systems. Moscow Univ Chem Bull. 2011 Aug;66(4):199–228.
Mewis J, Wagner NJ. Thixotropy. Vols. 147–148, Advances in Colloid and Interface Science. 2009. p. 214–27.
Klein B, Hallbom DJ. Modifying the rheology of nickel laterite suspensions. Miner Eng. 2002 Oct;15(10):745–9.
Annable T, Buscall R, Ettelaie R, Whittlestone D. The rheology of solutions of associating polymers: Comparison of experimental behavior with transient network theory. J Rheol (N Y N Y). 1993 Jul;37(4):695–726.
Sanson A, Gardini D, Montanari G, Galassi C, Roncari E. Key role of milling in the optimization of TiO2 nanoinks. J Mater Res. 2006 Jun;21(6):1561–9.
Umerova S, Dulina I, Ragulya A. Features of clusters formation in the system" polymer-plasticizer-nanopowder" under polymer crystallization conditions. Proc Int Conf Nanomater Appl Prop. 2014;3(1):6.
Kamibayashi M, Ogura H, Otsubo Y. Shear-thickening flow of nanoparticle suspensions flocculated by polymer bridging. J Colloid Interface Sci. 2008 May 15;321(2):294–301.
Brown E, Jaeger HM. The role of dilation and confining stresses in shear thickening of dense suspensions. J Rheol (N Y N Y). 2012 Jul;56(4):875–923.
Fan A, Turro NJ, Somasundaran P. A study of dual polymer flocculation. Colloids Surfaces A Physicochem Eng Asp. 2000 Mar 15;162(1–3):141–8.
Phair JW. Rheological analysis of concentrated zirconia pastes with ethyl cellulose for screen printing sofc electrolyte films. J Am Ceram Soc. 2008 Jul;91(7):2130–7.
Annable T, Buscall R, Ettelaie R. Network formation and its consequences for the physical behaviour of associating polymers in solution. In: Colloids and Surfaces A: Physicochemical and Engineering Aspects. Elsevier Science B.V.; 1996. p. 97–116.
Mewis J. Thixotropy - a general review. J Nonnewton Fluid Mech. 1979;6(1):1–20.
Martín-Gómez A, Gompper G, Winkler R. Active Brownian Filamentous Polymers under Shear Flow. Polymers (Basel) [Internet]. 2018 Jul 30 [cited 2020 Jan 29];10(8):837. Available from: http://www.mdpi.com/2073-4360/10/8/837
Moriana AD, Zhang S. Lead-free textured piezoceramics using tape casting: A review. Vol. 4, Journal of Materiomics. Chinese Ceramic Society; 2018. p. 277–303.
Uchino K. Multilayer Technologies for Piezoceramic Materials. In: Advanced Piezoelectric Materials. Elsevier; 2017. p. 423–51.
Min D, Zhou W, Qing Y, Luo F, Zhu D. Enhanced Microwave Absorption Properties of Oriented Carbonyl Iron/Carbon Black Composite Induced by Shear Force. J Electron Mater. 2017 Aug 1;46(8):4903–11.
Walton RL, Vaudin MD, Hofer A, Kupp E, Meyer RJ, Messing GL. Tailoring Particle Alignment and Grain Orientation during Tape Casting and Templated Grain Growth. J Am Ceram Soc [Internet]. 2018 Oct 9 [cited 2020 Jan 28];jace.16144. Available from: https://onlinelibrary.wiley.com/doi/abs/10.1111/jace.16144
Brennhaugen DE, Grande T, Astri I, Haugen B. Texturing of lead free piezoelectric ceramics.
Diaz JA, Wu X, Martini A, Youngblood JP, Moon RJ. Thermal expansion of self-organized and shear-oriented cellulose nanocrystal films. Biomacromolecules. 2013 Aug 12;14(8):2900–8.
Hansen CM, Pierce PE. Cellular Convection in Polymer Coatings-An Assessment. Ind Eng Chem Prod Res Dev [Internet]. 1973 Mar 1 [cited 2020 Feb 3];12(1):67–70. Available from: https://pubs.acs.org/doi/abs/10.1021/i360045a010
Kitano M, Shiojiri M. Benard convection ZnO/resin lacquer coating - A new approach to electrostatic dissipative coating. Powder Technol. 1997 Oct 15;93(3):267–73.
Lewis JA, Blackman KA, Ogden AL, Payne JA, Francis LF. Rheological Property and Stress Development during Drying of Tape-Cast Ceramic Layers. J Am Ceram Soc [Internet]. 1996 Dec [cited 2020 Feb 3];79(12):3225–34. Available from: http://doi.wiley.com/10.1111/j.1151-2916.1996.tb08099.x
Basics of thixotropy?:: Anton Paar Wiki [Internet]. [cited 2020 Jan 12]. Available from: https://wiki.anton-paar.com/en/basics-of-thixotropy/
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Copyright (c) 2021 Serhii Ivanchenko, S. Umerova, D. Baranovskyi, O. Kovalenko, A. Ragulya
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